Polaronic Hole Trapping in DopedBaBiO3

Multiphonon hole trapping from first principles

Nonradiative multiphonon capture of carriers into the gate dielectrics of metal-oxide-semiconductor systems and its involvement with the negative bias temperature instability is discussed. A simple method for the extraction of the line-shape function from an atomistic bulk defect model is suggested and applied to defect models in alpha quartz. Electronic structures are described using density f...

Design of a Hole Trapping Ligand.

A new ligand that covalently attaches to the surface of colloidal CdSe/CdS nanorods and can simultaneously chelate a molecular metal center is described. The dithiocarbamate-bipyridine ligand system facilitates hole transfer through energetic overlap at the inorganic-organic interface and conjugation through the organic ligand to a chelated metal center. Density functional theory calculations s...

Nonadiabatic polaronic superconductivity in MgB2 and cuprates

Tunable polaronic conduction in anatase TiO2.

Oxygen vacancies created in anatase TiO(2) by UV photons (80-130 eV) provide an effective electron-doping mechanism and induce a hitherto unobserved dispersive metallic state. Angle resolved photoemission reveals that the quasiparticles are large polarons. These results indicate that anatase can be tuned from an insulator to a polaron gas to a weakly correlated metal as a function of doping and...

Cotunnelling and polaronic effect in granular systems

We theoretically study the conductivity in arrays of metallic grains due to the variable-range multiple cotunneling of electrons with short-range (screened) Coulomb interaction. The system is supposed to be coupled to random stray charges in the dielectric matrix that are only loosely bounded to their spatial positions by elastic forces. The flexibility of the stray charges gives rise to a pola...